Crystal structure of a metastable form of indium orthovanadate, InVO4-I
Identifieur interne : 01CD90 ( Main/Repository ); précédent : 01CD89; suivant : 01CD91Crystal structure of a metastable form of indium orthovanadate, InVO4-I
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Abstract
The compound InVO4-I has been obtained with a good purity level from a chimie douce process. Using X-ray powder diffraction data, its crystal structure has been determined by analogy with isostructural compounds crystallizing with the so-called α-MnMoO4 type structure. The crystal symmetry is monoclinic (space group C2/m) and the unit cell parameters are a = 10.271(1) Å, b = 9.403(1)Å, c = 7.038(1)Å, and β = 105.08(1)°. The structure has been refined by the Rietveld method (RF = 0.030 and Rwp = 0.098 for 360 reflections). The structure is based on compact In4O16 groups of four edge-sharing InO6 octahedra linked to each other by VO4 tetrahedra. Each In4O16 cluster contains two In1O6 and two other In2O6 octahedra and the corresponding In1-O and In2-O mean distances are 2.14 and 2.17 Å. The mean value for the V-O bond length is 1.71 Å. Relationships with the stable indium vanadate and related phases are discussed.
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en" level="a">Crystal structure of a metastable form of indium orthovanadate, InVO<sub>4</sub>-I</title><author><name sortKey="Touboul, M" uniqKey="Touboul M">M. Touboul</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>CNRS Univ. Picardie Jules Verne, URA 1211 lab. réactivité chimie solides</s1><s2>80039 Amiens</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Picardie</region><settlement type="city">Amiens</settlement></placeName></affiliation></author><author><name sortKey="Melghit, K" uniqKey="Melghit K">K. Melghit</name><affiliation wicri:level="3"><inist:fA14 i1="01"><s1>CNRS Univ. Picardie Jules Verne, URA 1211 lab. réactivité chimie solides</s1><s2>80039 Amiens</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Picardie</region><settlement type="city">Amiens</settlement></placeName></affiliation></author><author><name sortKey="Benard, P" uniqKey="Benard P">P. Benard</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>CNRS Univ. Rennes I, URA 1495 lab. chimie solide inorganique moléculaire</s1><s2>35042 Rennes</s2><s3>FRA</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName></affiliation></author><author><name sortKey="Louer, D" uniqKey="Louer D">D. Louër</name><affiliation wicri:level="3"><inist:fA14 i1="02"><s1>CNRS Univ. Rennes I, URA 1495 lab. chimie solide inorganique moléculaire</s1><s2>35042 Rennes</s2><s3>FRA</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ></inist:fA14><country>France</country><placeName><region type="region" nuts="2">Région Bretagne</region><settlement type="city">Rennes</settlement></placeName></affiliation></author></titleStmt><publicationStmt><idno type="inist">95-0488554</idno><date when="1995">1995</date><idno type="stanalyst">PASCAL 95-0488554 INIST</idno><idno type="RBID">Pascal:95-0488554</idno><idno type="wicri:Area/Main/Corpus">01BF62</idno><idno type="wicri:Area/Main/Repository">01CD90</idno></publicationStmt><seriesStmt><idno type="ISSN">0022-4596</idno><title level="j" type="abbreviated">J. solid state chem.</title><title level="j" type="main">Journal of solid state chemistry</title></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Crystal structure</term><term>Experimental study</term><term>Indium Orthovanadates</term><term>Ternary compounds</term><term>XRD</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term><term>XRD</term><term>Structure cristalline</term><term>Composé ternaire</term><term>Indium Orthovanadate</term><term>6166F</term><term>InVO4</term><term>In O V</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The compound InVO4-I has been obtained with a good purity level from a chimie douce process. Using X-ray powder diffraction data, its crystal structure has been determined by analogy with isostructural compounds crystallizing with the so-called α-MnMoO<sub>4</sub> type structure. The crystal symmetry is monoclinic (space group C2/m) and the unit cell parameters are a = 10.271(1) Å, b = 9.403(1)Å, c = 7.038(1)Å, and β = 105.08(1)°. The structure has been refined by the Rietveld method (R<sub>F</sub> = 0.030 and R<sub>wp</sub> = 0.098 for 360 reflections). The structure is based on compact In<sub>4</sub>O<sub>16</sub> groups of four edge-sharing InO<sub>6</sub> octahedra linked to each other by VO<sub>4</sub> tetrahedra. Each In<sub>4</sub>O<sub>16</sub> cluster contains two In1O<sub>6</sub> and two other In2O<sub>6</sub> octahedra and the corresponding In1-O and In2-O mean distances are 2.14 and 2.17 Å. The mean value for the V-O bond length is 1.71 Å. Relationships with the stable indium vanadate and related phases are discussed.</div></front></TEI><inist><standard h6="B"><pA><fA01 i1="01" i2="1"><s0>0022-4596</s0></fA01><fA02 i1="01"><s0>JSSCBI</s0></fA02><fA03 i2="1"><s0>J. solid state chem.</s0></fA03><fA05><s2>118</s2></fA05><fA06><s2>1</s2></fA06><fA08 i1="01" i2="1" l="ENG"><s1>Crystal structure of a metastable form of indium orthovanadate, InVO<sub>4</sub>-I</s1></fA08><fA11 i1="01" i2="1"><s1>TOUBOUL (M.)</s1></fA11><fA11 i1="02" i2="1"><s1>MELGHIT (K.)</s1></fA11><fA11 i1="03" i2="1"><s1>BENARD (P.)</s1></fA11><fA11 i1="04" i2="1"><s1>LOUËR (D.)</s1></fA11><fA14 i1="01"><s1>CNRS Univ. Picardie Jules Verne, URA 1211 lab. réactivité chimie solides</s1><s2>80039 Amiens</s2><s3>FRA</s3><sZ>1 aut.</sZ><sZ>2 aut.</sZ></fA14><fA14 i1="02"><s1>CNRS Univ. Rennes I, URA 1495 lab. chimie solide inorganique moléculaire</s1><s2>35042 Rennes</s2><s3>FRA</s3><sZ>3 aut.</sZ><sZ>4 aut.</sZ></fA14><fA20><s1>93-98</s1></fA20><fA21><s1>1995</s1></fA21><fA23 i1="01"><s0>ENG</s0></fA23><fA43 i1="01"><s1>INIST</s1><s2>14677</s2><s5>354000053869590140</s5></fA43><fA44><s0>0000</s0></fA44><fA45><s0>25 ref.</s0></fA45><fA47 i1="01" i2="1"><s0>95-0488554</s0></fA47><fA60><s1>P</s1></fA60><fA61><s0>A</s0></fA61><fA64 i1="01" i2="1"><s0>Journal of solid state chemistry</s0></fA64><fA66 i1="01"><s0>USA</s0></fA66><fC01 i1="01" l="ENG"><s0>The compound InVO4-I has been obtained with a good purity level from a chimie douce process. Using X-ray powder diffraction data, its crystal structure has been determined by analogy with isostructural compounds crystallizing with the so-called α-MnMoO<sub>4</sub> type structure. The crystal symmetry is monoclinic (space group C2/m) and the unit cell parameters are a = 10.271(1) Å, b = 9.403(1)Å, c = 7.038(1)Å, and β = 105.08(1)°. The structure has been refined by the Rietveld method (R<sub>F</sub> = 0.030 and R<sub>wp</sub> = 0.098 for 360 reflections). The structure is based on compact In<sub>4</sub>O<sub>16</sub> groups of four edge-sharing InO<sub>6</sub> octahedra linked to each other by VO<sub>4</sub> tetrahedra. Each In<sub>4</sub>O<sub>16</sub> cluster contains two In1O<sub>6</sub> and two other In2O<sub>6</sub> octahedra and the corresponding In1-O and In2-O mean distances are 2.14 and 2.17 Å. The mean value for the V-O bond length is 1.71 Å. Relationships with the stable indium vanadate and related phases are discussed.</s0></fC01><fC02 i1="01" i2="3"><s0>001B60A66F4</s0></fC02><fC03 i1="01" i2="3" l="FRE"><s0>Etude expérimentale</s0><s5>01</s5></fC03><fC03 i1="01" i2="3" l="ENG"><s0>Experimental study</s0><s5>01</s5></fC03><fC03 i1="02" i2="3" l="FRE"><s0>XRD</s0><s5>02</s5></fC03><fC03 i1="02" i2="3" l="ENG"><s0>XRD</s0><s5>02</s5></fC03><fC03 i1="03" i2="3" l="FRE"><s0>Structure cristalline</s0><s5>03</s5></fC03><fC03 i1="03" i2="3" l="ENG"><s0>Crystal structure</s0><s5>03</s5></fC03><fC03 i1="04" i2="3" l="FRE"><s0>Composé ternaire</s0><s5>05</s5></fC03><fC03 i1="04" i2="3" l="ENG"><s0>Ternary compounds</s0><s5>05</s5></fC03><fC03 i1="05" i2="X" l="FRE"><s0>Indium Orthovanadate</s0><s2>NC</s2><s2>NA</s2><s5>06</s5></fC03><fC03 i1="05" i2="X" l="ENG"><s0>Indium Orthovanadates</s0><s2>NC</s2><s2>NA</s2><s5>06</s5></fC03><fC03 i1="05" i2="X" l="SPA"><s0>Ortovanadato</s0><s2>NC</s2><s2>NA</s2><s5>06</s5></fC03><fC03 i1="06" i2="3" l="FRE"><s0>6166F</s0><s2>PAC</s2><s4>INC</s4><s5>56</s5></fC03><fC03 i1="07" i2="3" l="FRE"><s0>InVO4</s0><s4>INC</s4><s5>92</s5></fC03><fC03 i1="08" i2="3" l="FRE"><s0>In O V</s0><s4>INC</s4><s5>93</s5></fC03><fC07 i1="01" i2="3" l="FRE"><s0>Composé minéral</s0><s5>04</s5></fC07><fC07 i1="01" i2="3" l="ENG"><s0>Inorganic compounds</s0><s5>04</s5></fC07><fN21><s1>275</s1></fN21></pA></standard></inist></record>Pour manipuler ce document sous Unix (Dilib)
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